making hard soap with potassium hydroxide

In this case, the soap calculator tells me that I need 6.13 ounces potassium hydroxide to turn this recipe into a 3% superfat. It is even more soluble compared with soap made with sodium hydroxide. This high-grade, high-quality product comprises of 90 percent pure flakes. calendula, comfrey, etc) in advance. It costs a bit more, but for spraying on the tender leaves of my plants, I want a better grade of soap. We use sodium hydroxide to make bar soap, potassium hydroxide to make liquid soap. For the sake of this article, we will be using the sodium hydroxide chart. Was curious is this recipe will make a hard with bar of soap with a good lather: 40% coconut oil 30% olive oil 5% castor oil 10%avocado oil ... which creates potassium hydroxide and is used for liquid soap. Make lye soap from sodium hydroxide and olive oil via the saponification reaction. Some soapers use both sodium and potassium hydroxide. Liquid soap worked well for cleaning and laundry but dilutes quickly and thus wastes more than hard soap; hard soap was prized for its economy but because of the lower availability of sodium hydroxide much more expensive. Then, add some potassium hydroxide flakes to a bowl of water and pour the mixture into the crockpot with the oils. However, from Gea Seeds recommend using potassium soap as an insecticide and acaricide to prevent the most common pests of the garden in an ecological and natural way. Sodium hydroxide is used to make hard bar soap while potassium hydroxide is used to make liquid soap. Each oil has its own saponification value: the number of milligrams of potassium needed to saponify (make into soap) one gram of oil. But then I … I do recommend letting it cure though so that it lasts a lot longer. Making Bar Soap. In early Renaissance, soap balls became in fashion which were made from store bought grated hard soap kneaded with botanicals and scents. They are the most chemically similar of the hydroxides. It is critical that the amount of base be kept to a minimum otherwise the soap produced can be very harmful to the skin," says Fenk. Have had no problems at all when using it for making my soap. This liquid soap is made with potassium hydroxide (KOH) using the cold processed liquid soap (CPLS) method. They are both a white, strong alkaline, corrosive solid or powder. Sodium Hydroxide (NaOH), also known as lye, is an essential ingredient in the soap making process. Comes in easy to open and use jar. Sodium Hydroxide lye is used to make hard soap where Potassium Hydroxide lye is used to make liquid soap. You can not make soap without lye and even surfactant is made with lye and then its pH is reduced that is why you will see on the labels of some natural shower gels stating surfactant from plant source or surfactant from coconut oil. They are prepared by reacting fats and oils with a strong base, such as sodium hydroxide or potassium hydroxide. Potassium Hydroxide (KOH) is used for making soft soaps, such as liquid or gel. Both types of lye are dissolved in a liquid, like distilled water or milk. The flakes are easier to work with, but are still caustic, so gloves and protective eyewear must be used. 20 Minutes Later. First lets analyze the types of soap you are making. With liquid soaps, the chemical reaction takes place with potassium hydroxide, which is a … While both sodium and potassium hydroxide are poisonous and corrosive chemicals on their own, once saponification occurs, they are rendered harmless. When the lye is dissolved in the water, add the mixture to the oils in the crock pot and stick blend until the mixture reaches trace. The 95 process of making soap is known as ‘saponification.’ Triglycerides derived from vegetable oils and animal 96 fats react with a strong base, such as potassium hydroxide. Make sure to … This alkali is deliquescent and readily absorbs moisture and carbon dioxide in air. The main difference between potassium and sodium soaps is consistency — usually, potassium makes a softer, more water-soluble soap than sodium. Amazon's Choice for potassium hydroxide for soap making. Potassium-based alkali soaps are more water soluble and make a softer soap (Example: liquid castile soaps). Our Potassium Hydroxide, sometimes called potash or lye, is food grade. Likewise, both compounds can be used to make biodiesel. Soaps are sodium and potassium salts of fatty acids. Both sodium and potassium hydroxide are caustic alkali metal compounds which are used to make lathering soaps. If the soap is made properly, the lye is used up in the saponification process to turn oil into soap. Whereas, potassium hydroxide (KOH) is used to make liquid (or soft) soaps." Potassium Hydroxide Flakes. When working with lye never use vinegar on your skin! The flakes are pretty thick and can be used for making baby shampoo, dishwasher soap, hand soap, and more. Your soap looks like really thick white soap... be careful, the lye is still very much … It is commonly used to made high quality, handmade liquid soap. 90% purity, flakes. Clarification: Lye refers to Potassium Hydroxide and Sodium Hydroxide as well as Potassium Carbonate. They used lye made from wood ashes which is potash or potassium hydroxide. All soap, whether liquid or hard, starts with a simple chemical reaction between oils and an alkali. Lye (Sodium Hydroxide) and Potassium Hydroxide Quality. Making hard and soft soap by means of saponification Paper details: This internship project consists of making hard and soft soap by means of saponification; chemical reaction between an acid and a base to form a salt. Potassium hydroxide lye is used to make liquid soap. How African Black Soap Is Made. Note that this reaction is exothermic - it will produce heat - and the fumes are toxic. Its function has always been to eliminate stains that are difficult to remove without damaging the fabrics. This solution, when mixed with fats and oils, will cause a chemical reaction called saponification. Using KOH for liquid soap is really the proper way to make liquid soap. Hard soaps typically contain sodium hydroxide and potassium hydroxide in soft soaps. After that, everything seems to change—or so I thought, from my reading. Saponification is a process by which triglycerides react with sodium or potassium hydroxide (lye) to produce glycerol […] This solution, when mixed with fats and oils, will cause a chemical reaction resulting in beautiful handmade liquid soap. Citric acid reacts with lye to make sodium citrate or potassium citrate, depending on whether your lye is NaOH or KOH. Feb 25, 2020 - Explore Bear Paw's board "KOH liquid soap" on Pinterest. To make your own lye for homemade soap from scratch, you’ll need to collect ashes from burnt hardwood. Sodium hydroxide (also called caustic soda) is used when making hard bars of soap. Chemicals and minerals require much more thorough care when using pots or in our garden, when we want to end pests. Potassium hydroxide is more soluble than sodium hydroxide, which makes liquid soap possible. Sodium hydroxide is favored for making solid Castile soap with potassium hydroxide used for liquid soaps. In cold-process soap making, you use Sodium hydroxide (NaOH) to create hard bars of soap. Potassium Hydroxide is still a dangerous chemical, and care needs to be taken when using it. Came out perfect every time! For my purposes, lye refers to any compound of high pH (alkaline aka basic) that are required for soap making or bucking animal hides. The alkaline medium used depends on the type of soap. Potassium soap is a 100% natural stain remover product. The lye to make soft and hard soaps with was made by leaching water through ashes; hardwood ashes for potassium hydroxide lye, and marine plant ashes like barilla for sodium hydroxide lye. Sodium Hydroxide is more commonly known as lye or caustic soda where Potassium Hydroxide is known as potash. I solved the problem by using a small amound in a foam dispenser, but maybe one day I can make real liquid soap. When either NaOH or KOH are combined with fat/oil and water, saponification occurs. They are not interchangeable, however. 4.7 out of 5 stars 776. They had a tip on their site that if you are making soft soap use potassium hydroxide with TEA (triethanolamine) and if you want hard soap use sodium hydroxide with the … Alibaba.com offers 1,012 potassium hydroxide soap making products. 1/3 sodium and 2/3 potassium will do it. Soap. With winter approaching, I explored ways to use the wood ash produced from my catalytic wood stove. Basic Definitions. So don’t freak out if that happens. Combined with sodium hydroxide (NaOH), it is a colorless solid and a strong prototype base. Add the potassium hydroxide to the water (never the other way around! Making your own Potassium Hydroxide Correction - This is actually Potassium Carbonate and Sodium Carbonate. Soaps are sodium and potassium salts of fatty acids. Lye (kOH) used in liquid soap making. edited 4 years ago. 94 Potassium hydroxide is also used to make soap from the reaction with potassium salts of fatty acids. A chelator does two things -- reduces the likelihood of rancidity (DOS) in the soap and it reduces the amount of sticky soap scum created when lye soap is used in water. There is no lye present in the finished bars of soap or shampoo. Most potassium hydroxide is 90% purity, but double check the brand you purchased. of salt per pound of oils in your lye mixture to make you soap bars harder. (A high range for liquid soap.) Anonymous - The foam seems to be unavoidable. Hard Soap: Hard soap is made using sodium hydroxide (NaOH) or lye. Water is best to rinse the skin area. In scientific terms, soap is defined as the sodium salt of a fatty acid. To make liquid soap, start by heating coconut oil, castor oil, olive oil, and jojoba oil in a crockpot. The stuff we’ll be making from ashes is potassium hydroxide, or potash. This premium product comes in secure packaging. Making Hard Soap with Potassium Hydroxide (KOH) Not certain if anyone is interested, but I have been on a mission to explore lately and just discovered an interest in making soap with KOH instead of... Pernille Jakobsen. Sodium hydroxide is most commonly used and what I assume this recipe calls for. Today, the process of making soap most commonly involves reacting an organic acid with an alkaline chemical like potassium hydroxide or sodium hydroxide.Industrially, the caustic soda base used most often is sodium hydroxide, which is also called lye. This type of lye is also known by common names including Caustic soda, Sodium hydrate, and Soda lye. Essential Depot Potassium Hydroxide Flakes KOH, 2 lbs Caustic Potash Anhydrous KOH Dry Electrolyte - HDPE Container with resealable Child Resistant Cap. Lye in the form of both sodium hydroxide and potassium hydroxide is used in making soap. Potassium hydroxide is an inorganic compound with the formula KOH. In a refinement known and used by many soap makers as early as the 1700s , the carbonate lye from ash was mixed with water and slaked lime (calcium hydroxide, Ca(OH)2) to form a hydroxide lye -- a mixture of potassium hydroxide and sodium hydroxide. It is a white solid, highly caustic metallic base and alkali salt. It is also commonly referred to as caustic potash. The remaining .01% of the mass within the canister is water vapor pulled from the air, due to the intense hygroscopic properties of lye. Modern liquid soap can be made by dissolving sodium hydroxide soap into water, which it does not like to do naturally, or by making soap with potassium hydroxide. Making soap with hydroxide lye -- Wood ash and lime method. Potassium hydroxide is used for making liquid soaps and soft shaving soaps and you won’t really get a hard bar out of it. Homemade lye water made from potassium hydroxide is ideal for making liquid soaps. These two lye saponify differently, are used at different rates, and result in different textured soaps. Make liquid soap. Certified Lye™ sells dry solid lye as 99.99% pure sodium hydroxide microbeads. Making cream soap is more complicated than making bar soap and liquid soap. Fun Decorating Tip: If you like to make hard soap as well, set that into molds and then pipe the whipped soap on top for a fun play on texture and shape. NaOH is used to make hard bars of soap while KOH is used to make liquid soaps. You can also make paste soap which is pretty cool. A wide variety of potassium hydroxide soap making options are available to you, If you want hard bar soap you will need to use sodium hydroxide and if you are making liquid soap you will need potassium hydroxide. It has the lowest pH of any soap I have made (7 on litmus paper). Palm oil has a SAP value of .141. To make the sodium salt (or soap) a reaction between a fatty acid and an alkaline needs to take place. Carefully measure the potassium hydroxide, and slowly pour into the water. Mix the Ingredients. All the Best! The Secret To Hard Soap. Dual-lye recipes are often used for specialty soaps such as cream soap, shave soap, and liquid soap. Soapmaking is an ancient technique which includes the mixing of water, a solution formed from burned wood ashes and … Like our American grandmothers' old-fashioned lye soap, this soap was made with potassium hydroxide (KOH) derived from wood ashes and is a soft paste, rather than a hard bar-type soap. This reaction breaks the ester bond, which If you’re not familiar with that term, hardwood trees are generally deciduous, with dense wood. Monday 4th of November 2019. This alkali is deliquescent and readily absorbs moisture and carbon dioxide in air. Sodium Hydroxide (NaOH) is used for making hard soap, such as for bars. Household ammonia solution (5% NH4OH in water) is used in some older soap recipes, especially ones for lard-based household cleaning and laundry soaps. One more note, I am one of those risk taking soapers who doesn’t even wear gloves when making soap. If we do not go carefully, it is more than likely that we will end up killing the plant, so all our effort will have resulted in vain. SOAP MAKING DAY Saponification is a process by which triglycerides react with sodium or potassium hydroxide (lye) to produce glycerol and a fatty acid salt called "soap." Because I read somewhere that potassium hydroxide - from hardwood - is for liquid soap and sodium hydroxide for hard soap bars. Liquid soap is made with a type of lye called potassium hydroxide.This is the lye you want.. Potassium hydroxide is different from sodium hydroxide, the drain cleaner lye used to make a hard bar soap.. "EXCELLENT QUALITY POTASSIUM HYDROXIDE FLAKES "COMMENTS: Excellent quality potassium hydroxide in flake form. Boiling the ashes of a fire, particularly hardwood, would produce pot ash or potassium hydroxide. In liquid soap making, you use a different type of lye called Potassium hydroxide (KOH). From my reading it would appear that the characteristics of KOH and K2CO3 soap is the same. Potassium soap is a 100% natural stain remover product. Its function has always been to eliminate stains that are difficult to remove without damaging the fabrics. However, from Gea Seeds recommend using potassium soap as an insecticide and acaricide to prevent the most common pests of the garden in an ecological and natural way. Lye For Liquid Castile Soap. Sodium hydroxide lye is used to make solid cold process soap. Because of the lack of information on the internet about KOH hard bar soap i had to wing it but it worked. Making Soap 31 Introduction Soap-making is an ancient craft and one of the oldest known chemical reactions involving organic compounds. The answer is "No." The heat will melt down the fats into liquid form so that they can solidify with … Sodium Hydroxide (NaOH) and Potassium Hydroxide (KOH) are almost interchangeable. Remember that these are two very different things: lye, or sodium hydroxide, is used to make hard bar soap; potassium hydroxide is used to make liquid soap. Sodium hydroxide is used for bar soap… Melt the coconut oil along with the other oils in a large crock pot. All regular soap is made from caustic soda (lye or also called sodium hydroxide). Potassium hydroxide is the type you would be able to make from wood ash. You might be able to find some videos of it being made. These strong bases go by various names, caustic soda or potash, which is NaOH, sodium hydroxide or KOH, potassium hydroxide or just plain lye. You can make bar soap with KOH if you load it up with hard fats and prepare for a long cure time. See more ideas about liquid soap, soap, liquid. Hydroxide reacts chemically with oil, fat or wax to produce soap. Potassium hydroxide is a bit different than sodium hydroxide in that it hisses while it dissolves! Liquid Soap Making. Potassium hydroxide is more soluble in water, ethanol and methanol than its’ counterpart Sodium Hydroxide. I would like to know if it is possible to make a soap bar from potassium hydroxide. It is fine on counters to neutralize. A soap calculator is the best way to determine how much lye to use based on the amount of oils and butters you are using. Views: 697,049. To harden it into bars she said they added table salt after it all came together. 2. Potassium hydroxide derived Castile soaps are more easily dissolved and diluted in water and are hence favored for liquid soap production for this reason. When sodium hydroxide is used, a hard soap is produced. In addition to being softer, this type of soap has a lower melting point. Oils are an extremely important component of the soap making process, and without oil (or fatty acids of oils) the saponification reaction can’t take place. Updated: September 30, 2019. $ 8.95 – $ 34.95. Article Summary X. The qualities of the soap will vary when different oils are used in the formula. Potassium hydroxide is a dangerous and corrosive substance that can cause severe damage to the skin, eyes, digestive, and respiratory system with acute and prolonged exposure and contact. "The type of base (NaOH or KOH) determines the kind of soap. The result of saponification is beautiful handmade soap. Traditional Beldi soaps were made with olive oil--the material most readily available for soap making in the Middle East. The old stuff was made with potash, Potassium Hydroxide. I recently made a Potassium Hydroxide (Potash) salt hard bar and am really happy with it. In manufacturing soaps, both potassium hydroxide and sodium hydroxide are used in saponification, a process that converts fats into soap. Liquid soap requires a different type of lye–potassium hydroxide (caustic potash). Sea salt is awesome. Potassium hydroxide soaps are softer and more easily dissolved in water than sodium hydroxide soaps. Either type of citrate works as a chelator in soap. You can also make your own castile soap, which uses a lot of fat to make a moisturizing soap. Modern potassium hydroxide soaps are similar to medieval soft soap, as potash lye is the natural form of potassium hydroxide; with contaminants and of uncertain strength. $19.58 $ 19. 58 ($0.61/Ounce) $29.99 $29.99. Stir gently so all of the potassium hydroxide dissolves. The primary difference between liquid soap and bar soap is the type of lye you use to convert the oils into soap. Also called caustic potash, it will not create solid soap and instead results … Through the action of the hydroxide ions, the free fatty acids are transformed into soap. A saponification chart or saponification table takes out the guesswork of soap making and wondering how much lye or caustic soda, also known as sodium hydroxide, you should be adding to each type of fat that you decide to use. To make your own Potassium Carbonate, or potash you collect ashes and percolate water through them and collect it. Making Liquid Soap from Scratch Gather ingredients. Get the right equipment. Heat the oils. Make the lye solution. Add the lye solution to the oils. Cook the paste. Dilute the paste. Add fragrance and color. Store the soap. The mixed solution is extremely alkaline and if it comes in contact with your skin, it begins to absorb the oils and turns your skin into soap. Sodium hydroxide and potassium hydroxide are not interchangeable in either the proportions required or the properties produced in making soaps. Bar soap uses sodium hydroxide. Laboratory Experiments for General, Organic and Biological Chemistry 1 Making Soap 31 Introduction Soap-making is an ancient craft and one of the oldest known chemical reactions involving organic compounds. Lye soap This has a much smoother, silkier look and feel to it. If you are planning to try your hand at liquid soapmaking, then this potassium hydroxide flakes would come to good use. You can also make 2 batches of whipped soap, 1 that’s harder (using 80% hard oils and 20% soft oils) and 1 that’s softer (using 60% hard oils and 40% soft oils). There are two main types of lye used in soap making: sodium hydroxide and potassium hydroxide. (I use Essential Depot or Bramble Berry with good results.) Soap scum is created by the reaction that occurs when soap is combined with metal contaminants in hard water like calcium and magnesium. Hard soaps are especially good cleansers in hard water that contains magnesium, chloride, and calcium ions. In the example above the cocoa butters sodium hydroxide SAP value is 138. With black soap the water is seared out of it in the final stage and the soap is dried overnight. Read more about potassium hydroxide here. If we were going to use ten ounces of cocoa butter. Soap Test. With bar soaps, the chemical reaction takes place with sodium hydroxide. Saponification is the reaction from mixing these oils with an alkaline base - commonly this is Sodium Hydroxide (NaOH) or Potassium Hydroxide (KOH). Potassium hydroxide (KOH) - KOH is the caustic substance used to turn skin-loving oils and butters into soap. So you could take 6.13 oz needed – 3.97 already used = 2.16 ounces that you could dilute with 3x as much water and stir into the batch while rebatching in a crockpot. Most soap these days is made from Sodium Hydroxide, it is cheaper and makes a harder soap. The chemical reaction of making soap, called saponification, is complete, the lye and oil molecules have combined and chemically changed into soap and glycerin. I do not know for sure, but Ca(OH)2 is a much weaker base than sodium or potassium and will probably be unable to hydrolyze the fatty acids. Projects To Try. Experiment 718: Making Soap - Saponification . We would multiply the ten ounces of cocoa butter by .138. Soft Soap: Soft soap is made using potassium hydroxide (KOH) rather than sodium hydroxide. And, because it is a hot process soap, it can be used as soon as it is hard. Section 1: Purpose and Summary . 209 followers. Water - Water is used to dissolve the caustic to make soap. The reason I add liquid glycerin to my lye solution when making liquid soap is that it acts as a solvent and helps the oils + potassium hydroxide trace and turn to soap … In the first box, choose “Hybrid Soap” and the ratio of potassium hydroxide and sodium hydroxide you’d like to use. Kathryn. You’ll need to have Potassium Hydroxide for liquid soap (also known as Potash). When sodium hydroxide beads or flakes are mixed with a liquid, a lye solution is created. The triglycerides are most often animal fats or vegetable oils. I did find a page about making soap from lye made with wood ashes and it says to add 1/2 tsp. Using potassium hydroxide results in a soft soap. How to Make Liquid Hand Soap Perfect for making liquid soap bases for shampoo, body wash, laundry detergent, hand soap, etc. Liquid soap uses a different kind of lye than bar soap. The same safety precautions remain–use goggles and gloves when handling potassium hydroxide, avoid inhaling fumes, and store securely out of reach of children and pets. Potassium hydroxide lye is not ideal for making hard … Participates in many applications. Potassium hydroxide is harder to find and comes in flakes, not beads. *** Hazardous Material Notice *** THIS SHIPMENT IS CLASSIFIED AS ORM-D CONSUMER COMMODITY. For liquid or very soft soap potassium hydroxide is normally used and for a hard bar sodium hydroxide is used. Do not breathe over the bowl and stand away as you stir. While potassium hydroxide tends to yield soft, highly soluble soaps, sodium hydroxide produces the opposite, and has long been used to make ordinary bar soap. Many of us must have studied that in this process of saponification; if the sodium hydroxide is used then the hard soap will be produced and potassium hydroxide will produce the soft one. The biggest difference between this soap and other conventional cold or hot process soaps is that we are going to be using both sodium hydroxide (lye) and potassium hydroxide (KOH). Potash soap This soap is more grainy and crumbly. One of the most common was to make soap was with ashes from a fire that were boiled. Also known as KOH or Caustic Potash, it is a colorless white solid commonly found in flake, pellet or powder form.Like sodium hydroxide, potassium hydroxide is an essential ingredient in soap making as you can’t make soap without lye. Saponification Chart for Soap Making. The potassium soap is one of those products that we can use for plants to stay in perfect health condition. You see, lye (sodium hydroxide) is formed when wood ash (which is mostly potassium carbonate) is mixed with water. The resulting soap will be softer and dissolve more readily in water than a corresponding NaOH soap, though. Elaine White, the American Soapmaker, is responsible for the following chart. Sodium Hydroxide makes a hard soap and potassium hydroxide makes liquid soap. Soap: A compound made of natural fats, oils, or butters and a strong alkali such as sodium hydroxide (also called caustic soda), or potassium hydroxide (also called caustic potash). Cream soap is a hybrid of the two, made using both sodium hydroxide and potassium hydroxide, together, to make soap staying at cream consistency. When you add the potassium hydroxide it will sound like it is going to explode or boil over, but the water does not bubble up at all and it doesn’t even heat us as much as sodium hydroxide so don’t worry. and you should be wearing goggles and gloves). Now lets look at the chemical used in each of the variations. Stir the mixture continuously until it thickens. Never leave lye exposed to open air; replace the lid when not in use. In Soap Making: When potassium hydroxide flakes are mixed with a liquid, a basic solution is created. Postassium hydroxide the lye used to make liquid soap is much more preferable than using sodium hydroxide for bar soaps, there are a lot of shaving soap that use potassium hydroxide only and some use a dual lye usually 60% to 70% potassium hydroxide and 40 to 30% sodium hydroxide. Potassium Hydroxide Lye Flakes ( KOH) Potassium hydroxide is lye for soft and liquid soap making. Because more soapmakers use lye (sodium hydroxide), good soap calculators allow you to choose NaOH (lye) or KOH (potassium hydroxide). You can source this from your local soap store or, pick up from Essential Depot on Amazon. Liquid soap uses potassium hydroxide. Soap made with ammonium hydroxide (NH4OH) solution is slightly more water soluble than soap made with potassium hydroxide. Using infused oil: prepare your infused oil (ie. They are prepared by reacting fats and oils with a strong base, such as sodium hydroxide or potassium hydroxide.

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